Carbon materials for catalysis - download pdf or read online

By Philippe Serp

ISBN-10: 047017885X

ISBN-13: 9780470178850

This is often the 1st accomplished booklet protecting all elements of using carbonaceous fabrics in heterogeneous catalysis. It covers the coaching and characterization of carbon helps and carbon-supported catalysts; carbon floor chemistry in catalysis; the outline of catalytic, photo-catalytic, or electro-catalytic reactions, together with the advance of recent carbon fabrics similar to carbon xerogels, aerogels, or carbon nanotubes; and new carbon-based fabrics in catalytic or adsorption procedures. this can be a optimal reference for carbon, inorganic, and actual chemists, fabrics scientists and engineers, chemical engineers, and others.

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Liquid mesophase). For example, the very much engrained concept of a graphitized carbon black [275–277] makes no sense, because carbon blacks are far from being graphitizable. One persistently puzzling experimental fact in solid-state transformations of carbons exposed to HTT is the relative growth of crystallite width (La ) and crystallite height (Lc ). It remains essentially unexplored since Franklin’s incisive and influential discussions based on her pioneering x-ray diffraction analyses [273].

In the direction (a and b axes) parallel to the basal plane, the dominant chemistry in graphene is that of the very strong aromatic C–C bond; in the direction (c-axis) perpendicular to the basal plane, the weak van der Waals or π–π interactions are dominant. Such structural anisotropy often leads to anisotropy of properties, and during manufacture this can often be translated into a key advantage of carbon-based products. , 390 W/m/K in the ab-direction and 2 W/m/K in the c-direction) [11]. The electronic or electrical properties of carbons are a most immediate consequence of their structure.

1), the key issue is the degree of anisotropy. At the nanometer scale, all sp2 carbon materials are intrinsically anisotropic, as is well known. In the direction (a and b axes) parallel to the basal plane, the dominant chemistry in graphene is that of the very strong aromatic C–C bond; in the direction (c-axis) perpendicular to the basal plane, the weak van der Waals or π–π interactions are dominant. Such structural anisotropy often leads to anisotropy of properties, and during manufacture this can often be translated into a key advantage of carbon-based products.

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Carbon materials for catalysis by Philippe Serp


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